Solvents used in detailing products

Discussion in 'Car Detailing Product Discussion' started by togwt, Mar 30, 2009.

  1. togwt

    togwt Nuba Guru

    Solvents

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    In the interest of full disclosure, I am in no way affiliated with, employed by, have any vested interest, or in any way receive compensation from the sale or distribution of the product lines reviewed or the company that manufactures or markets it.

    Results Obtained
    These articles are not intended to warrant or guarantee any results with any of the products mentioned. No endorsement of companies or their products mentioned is intended, nor is criticism implied of similar companies or their products not mentioned. The author does not provide, nor guarantee and is not responsible or liable for any third-party products or services. Brand, product and company names used throughout these articles are trademarks of their respective companies and are used for product identification purposes only.

    Proper Technique
    The detailing methods set out here have been adapted for special use and may not be the same as those recommended by the product manufacturer, and you may experience different results from those stated. When in doubt always use common sense. A sound understanding of the proper technique and the correct process will produce excellent results even with a mediocre product. A quality product used without the proper surface preparation or application technique will never obtain a satisfactory result. Using the proper methodology (surface preparation, using a quality product, along with the correct application technique) will ensure an excellent result.

    Skill Level / Experience
    Some methods described may be beyond the capabilities of the average detailer or enthusiast; in this case we strongly encourage the reader to consult a professional detailer or body shop concerning the matters discussed herein.

    Liability
    The information contained herein is believed to be true and accurate; however we make no guarantees concerning the veracity of any statement. The writer assumes no responsibility, expressed or implied, due to misuse or misinterpretation of the information or methods used, or for any vehicle damage or injury that may occur due to the suggestions and information offered.

    Product Quality and Technique
    Proceed with this in mind; the products you use constitute a very small factor in the equation. Methodology and technique constitute 95%; the reasoning behind the choice of quality products is to eliminate any limiting factors, thus enabling you to place emphasis on technique used. There is no `one correct way' to apply a product; the way detailing products are customized are what each individual finds give them their desired results.

    Aesthetics
    The aesthetics- of a vehicles appearance is very subjective to say the least, the only best wax or sealant that really matters is what looks 'best' to you. In the final analysis it all come down to; 85% preparation, 5% product, 7% application methodology and the balance is in the ‘guy’ of the beholder

    Research
    Research others opinions and products, test them and then make an objective decision based upon factual information not marketing hype or brand loyalty. I have always thought that the more facts and information you have at hand the easier it is to judge what information you are being given. After all, how can you fully understand and properly use any product unless you have all the facts?

    Detailing products
    No endorsement of companies or their products mentioned is intended, nor is criticism implied of similar companies or their products not mentioned. The author does not provide any guarantee of results and is not responsible or liable for any third-party products or services. Brand, product and company names used throughout these articles are trademarks of their respective companies and are used for product identification purposes only. Car care chemicals are the most misunderstood component auto detailing, they should work on their real merits, not ‘smoke and mirrors'. Proceed with this in mind; the products you use constitute a very small factor in the equation. Disclaimer
    The information contained herein is believed to be true and accurate; however we make no guarantees concerning the veracity of any statement. Use of any information on this page is at the reader's own risk. The detailing methods set out here have been adapted for special use and may not be the same as those recommended by the product manufacturer, and you may experience different results from those stated. When in doubt always use common sense

    Solvents
    A solvent is a liquid or gas that dissolves a solid, liquid, or gaseous solute, resulting in a solution.
    [: when one substance is dissolved into another, a solution is formed; as opposed to a mixture where one compound is added to another and no chemical bond is formed]

    The most common solvent in everyday life is water. Most other commonly-used solvents are organic (carbon-containing) chemicals. These are called organic solvents. Solvents usually have a low boiling point and evaporate easily or can be removed by distillation, leaving the dissolved substance behind. To distinguish between solutes and solvents, solvents are usually present in the greater amount. Solvents can also be used to extract soluble compounds from a mixture; the most common example is the brewing of coffee or tea with hot water.

    Solvents are usually clear and colourless liquids and many have a characteristic odour. The concentration of a solution is the amount of compound that is dissolved in a certain volume of solvent. The solubility is the maximal amount of compound that is soluble in a certain volume of solvent at a specified temperature. Common uses for organic solvents are in dry cleaning (e.g. tetrachloroethylene), as paint thinners (e.g. toluene, turpentine), as nail polish removers and glue solvents (acetone, methyl acetate, ethyl acetate), in spot removers (e.g. hexane, petrol ether), in detergents (citrus terpenes), in perfumes (ethanol), and in chemical syntheses.

    Density
    Most organic solvents have a lower density than water, which means they are lighter and will form a separate layer on top of water. An important exception: many halogenated solvents like dichloromethane or chloroform will sink to the bottom of a container, leaving water as the top layer. This is important to remember when partitioning compounds between solvents and water in a separatory funnel during chemical syntheses.

    The reasoning for the use of solvents for the removal of bituminous asphalt is that it dissolves it as a means of removal, as opposed to rubbing it, tar is waterproof so water alone will not remove it (although warm water will soften it). Asphalt is very sticky and its presence on your paint means that harder particulate matter (dirt/grit) has also stuck to it. By agitating or rubbing the dirt/grit that is contained with the bituminous asphalt will cause surface marring or possibly scratching, dissolution alleviates any potential surface damage.

    Safe Solvent
    Solvents are used for chemical cleaning, and as a carrier system, it also makes products workable and to provide spread ability, as is the case with Carnauba wax, which in its natural state is rock hard.

    The low surface tension of silicones is sometimes added to solvents to improve the wetting ability and to improve the surface contact. Solvents require an aerobic cure (exposure to air) to allow them to evaporate (outgas); some solvents contain formaldehyde, which dissolves both natural rubber and synthetic compounds, and some contain petroleum distillates specifically hydrocarbon and oxygenated solvents, which represent most of the total organic solvents used.

    Organic solvents
    Can be classified by chemical structure, for example water is a solvent, but is inorganic. Solvents provide solubility for the other ingredients, dependant upon the type of solvent used will determine the product's drying time.

    Use a safe solvent; d-Limonene (3M Citrus Base Spray Adhesive Remover or P21S Total Auto Wash) that does not contain any harmful components (butyl, heptanes or xylene or hydrocarbon aliphatic solvents) With all cleaning products (especially solvents) always test a small inconspicuous area first to ensure it won't discolour, stain or etch the surface, and ensure that the pH of the product is suitable for the material After the paint surface has been subjected to a chemical cleaning its protective layer (s) have been removed and the paint surface left without protection, so it is very important that a wax or polymer protection be applied immediately.

    3M Citrus Base Spray Adhesive Remover – a citrus-based, solvent-free adhesive remover leaves surfaces clean and dry with no residue. Removes marker graffiti from white boards and tape residue from masking, foam or duct tape. Clean, fresh citrus scent - not recommended for use on plastic

    There are three main types:
    1. Oxygenated Solvents- alcohols, glycol ethers, ketones, esters, and glycol ether esters. Oxygenated solvents are synthesized from other chemicals to form the desired solvent. Those solvents are typically of a high purity with specifications ranging from 99.0% to 99.9% purity.
    2. Hydrocarbon Solvents (Petroleum Distillates) - aliphatic (include methane, propane, and kerosene, they are flammable and may be explosively flammable).
    3. Aromatic hydrocarbons- (are the most toxic compounds found in petroleum products and include such substances as para-xylene (benzene, toluene, ethyl benzene, and xylene), which are all volatile organic compounds (VOC) (See also Petroleum Distillates)
    Notes- when using solvents always use Nitrile medical gloves (usually the blue or purple ones) if you are going to be using them for any length of time.

    A safe solvent that does not contain any harmful components (heptanes or xylene or hydrocarbon aliphatic solvents (Stoner™ Tarminator or New Car Prep , simply emulsifies and dissolves the bituminous asphalt / tar /grease when you spray it directly on the paint film surface It is important not to leave a solvent based chemical on the paint finish longer than is necessary. Simply apply to the affected area, allow sufficient dwell time, and carefully wipe off, you may have to apply it three or four times allowing plenty of "dwell time" between applications.

    Other uses –it can also dissolve a variety of oil and petroleum based products, it's safe to use on all types of paint, plastics, synthetic fibres, carpet and upholstery. If used on vehicle paintwork re-apply a protect rant after use it will dissolve chewing gum and adhesives. Use to de-tar wheel rims after cleaning, will also remove shoe scuffmarks from vinyl trim, and can be used to remove tree sap or fuel stains from paint surfaces.

    With all cleaning products (especially solvents) always test a small inconspicuous area first to ensure it won't discolour, stain or etch the surface, and ensure that the pH of the product is suitable for the material

    After the paint surface has been subjected to a chemical cleaning its protective layer (s) have been removed and the paint surface left without protection, so it is very important that a wax or polymer protection be applied immediately.

    Notes- Use caution if you use WD-40 as it contains strong hydrocarbon (aliphatic) solvents, which may cause the paint surface to become clouded (opaque) or compromise non-neoprene rubber, it is also highly flammable (easily ignited by heat, sparks or flames) Don’t let it drip onto the brake pads as they will become ineffective and / or grab and squeal (MSD) – http://www.wd40.com/Brands/pdfs/msds-wd40_aerosol.us.pdf

    Solvent-based silicone dressings; Dimethalsilicone (DMS) usually a clear greasy liquid, which leaves a never-dry gloss film, most contain petroleum distillate solvents. Silicone is inert, it’s the solvent that damages the rubber, as it acts as a cleaning agent, as a result, the tyre begins to crack and rot. After the antiozonant works its way to the outside of the tyre and is exposed to the ozone in the air, it turns brown.

    The technical term for this effect is blooming, which then removes the elasticity from vinyl, rubber and paint; causing them to evaporate out of the substrate, expelling the rubber additives to the tyres surface and could result in premature drying and cracking, leaving behind a dry inflexible surface. Many tyre manufacturers (Goodyear, Michelin, etc) have issued technical service bulletins advising against the use of tyre dressings containing DMS silicone.

    The difference between water and solvent based is in the carrier system used. Solvent based products use a hydrocarbon silicone to suspend the product. When you apply it, the solvent evaporates leaving the dressing's active ingredients (silicone oil) behind; this type of silicone leaves a high gloss shine and will repel water longer but it is non-biodegradable. Most high gloss products are based upon (DMS) for vehicles fitted with ceramic brakes and / or pads PDS silicone products are not recommended as it can contaminate the pads and render them ineffective

    Chemical Name: Benzene
    Synonyms: Benzol, Cyclohexatriene
    • Effects on Vehicle: Paint streaking, damage
    • Health Effects: Carcinogenic
    • Found In: Solvents, Compounds

    Chemical Name: Toluene
    Synonyms: Toulon, Methylbenzene
    • Effects on Vehicle: Paint streaking and damage
    • Health Effects:
    • Central nervous system depression, cardiac disrythmia
    • Found In: Solvents, Compounds

    Chemical Name: m-Xylene
    Synonyms: Meta-Xylene, 1,3-Dimethylbenzene, m-Xylol
    • Effects on Vehicle: Paint streaking and other damage
    • Found In: Solvents, Compounds

    Environmental Commitment- please dispose of all non-biodegradable materials from your vehicle cleaning in a responsible manner

    Information resource

    1 The American Solvents Council (ASC) represents major hydrocarbon and oxygenated solvents manufacturers and users
    2.Wikipedia Encyclopedia- Wikipedia, the free encyclopedia
    3.Automotive Detailing Inside & Out; a Knowledge Base for the Perfectionist, by Jon Miller
    4. TOGWT™ Series of Detailing Articles, by Jon Miller

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    Detailing Articles
    This is one of is one of a series of unbiased and informative, knowledge based, subject specific articles, which are dedicated to the automotive detailing enthusiast or professional detailer in search of development and further education The purpose of these articles is to show you various ways, utilizing various skills and experience levels, on how to retrieve the original or better appearance / finish to your vehicles bodywork and its interior and how to preserve and maintain it, along with product recommendations and there correct application methods.

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